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  • biodiesel production from used cooking oil by two-step heterogeneous catalyzed process

    جزئیات بیشتر مقاله
    • تاریخ ارائه: 1390/01/01
    • تاریخ انتشار در تی پی بین: 1390/01/01
    • تعداد بازدید: 584
    • تعداد پرسش و پاسخ ها: 0
    • شماره تماس دبیرخانه رویداد: -
     the present study demonstrates the production of biodiesel from used cooking oil containing high free fatty acid by a two-step heterogeneously catalyzed process. the free fatty acids were first esterified with methanol using a 25 wt.% tpa/nb2o5 catalyst followed by transesterification of the oil with methanol over zno/na-y zeolite catalyst. the catalysts were characterized by xrd, ft-ir, bet surface area and co2-tpd. in the case of transesterification the effect of reaction parameters, such as catalyst concentration, methanol to oil molar ratio and reaction temperature, on the yield of ester were investigated. the catalyst with 20 wt.% zno loading on na-y exhibited the highest activity among the others. both the solid acid and base catalysts were found to be reusable for several times indicating their efficacy in the two-step process.

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