محبوبترین نویسندگان :
نویسندگان مقالات پربازدید :
مجله مهندسی شیمی
جزئیات رویداد
همایش ، رویداد ، ژورنال
اینستاگرام تی پی بین
حوزه های تحت پوشش رویداد

  • effect of carbon and nitrogen co-doping on characteristics and sonocatalytic activity of tio2 nanotubes catalyst for degradation of rhodamine b in water

    نویسندگان :
    کلمات کلیدی :
    جزئیات بیشتر مقاله
    • تاریخ ارائه: 1392/01/01
    • تاریخ انتشار در تی پی بین: 1392/01/01
    • تعداد بازدید: 635
    • تعداد پرسش و پاسخ ها: 0
    • شماره تماس دبیرخانه رویداد: -
     carbon and nitrogen co-doped titanium dioxide nanotubes (c—n co-doped tio2 nts) catalysts were successfully synthesized using a hydrothermal method at n:ti molar ratios between 0.1 and 1.0. transmission electron microscope (tem), x-ray diffraction (xrd), fourier transform infrared (ftir), x-ray photoelectron spectroscope (xps), uv–vis diffuse reflectance spectroscope (uv–vis drs) and surface area analyzer were used to characterize the synthesized catalysts. urea doping at n:ti = 0.3 led to the highest sonocatalytic activity with an apparent-first-order rate constant of 0.0226 min−1 as compared to 0.0098 min−1 for the un-doped tio2 nts. the high performance was associated with the synergistic effects between the doped c and n atoms, higher surface area and lower band gap energy. it was also ascribed to the creation of surface oxygen vacancies due to the formation of ti3+ species and better crystallinity of anatase phase as compared to the un-doped tio2 nts. most of the nitrogen atoms were bonded to oxygen atoms in the interstitial sites (ti—o—n and ti—n—o), but only minority of them could substitute the sites of oxygen atoms (n—ti—o). c atoms evidently presented in the form of ti—c and a complex carbonate species on the catalyst surface.

سوال خود را در مورد این مقاله مطرح نمایید :

با انتخاب دکمه ثبت پرسش، موافقت خود را با قوانین انتشار محتوا در وبسایت تی پی بین اعلام می کنم
مقالات جدیدترین رویدادها
مقالات جدیدترین ژورنال ها