V2O5-doped Na0.5K0.5NbO3-LiSbO3-BiFeO3 (KNN-LS-BF) lead-free piezoelectric ceramics were prepared by the traditional sintering method, and their temperature stability was studied. Characterization of the temperature dependences of dielectric and piezoelectric properties of the V2O5-doped KNN-LS-BF ceramics showed that V2O5 doping could significantly improve the temperature stability in the temperature range of 30°C to 420°C and cause a downward shift in the orthorho...