• the effects of cu(ii) ion as an additive on nh3 loss and co2 absorption in ammonia-based co2 capture processes

    جزئیات بیشتر مقاله
    • تاریخ ارائه: 1392/01/01
    • تاریخ انتشار در تی پی بین: 1392/01/01
    • تعداد بازدید: 563
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     chemical co2 absorption is one of the most cost- and energy-intensive processes in carbon capture and storage (ccs) technology. among various absorption processes, ammonia-based processes attract much attention, due to many benefits: high co2absorption rate and low energy consumption for ammonia regeneration. ammonia-based processes, however, have a problem to be solved for practical implementation due to the high vapor pressure of ammonia, which incurs ammonia loss during regeneration. in this study, the effect of cu(ii) ion as an additive on nh3 loss and co2absorption was investigated to examine the potential of cu(ii) ion to enhance the economic performance of ammonia-based processes. continuous operations were conducted with and without the addition of cu(ii) ion. the results showed that the addition of cu(ii) ion noticeably decreased nh3 loss in the regeneration process due to the complexation of copper and ammonium ions, i.e., [cu(nh3)4]2+. the cu(ii) addition also increased the co2 absorption capacity in the absorption process because ammonia concentration remained higher. in conclusion, cu(ii) ion can be used to reduce ammonia make-up cost and to enhance co2 absorption performance in ammonia-based co2capture processes.

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