• synthesis, characterization and phosphonium compounds by 1 and 3 bis (chloromethyl) benzene and benzyl bromide and their complexes with mercury

    نویسندگان :
    جزئیات بیشتر مقاله
    • تاریخ ارائه: 1395/09/20
    • تاریخ انتشار در تی پی بین: 1395/09/20
    • تعداد بازدید: 287
    • تعداد پرسش و پاسخ ها: 0
    • شماره تماس دبیرخانه رویداد: -

    phosphonium salts have the general formula r4p+x- and are derived from the sub-ion phosphonium tetrahedral (ph+4), such as phosphonium iodide [p(ch3)+4]-. generally, phosphonium is attributed to an organic derivative, such as tetra-phenyl phosphonium chloride and tetra tetra-methyl phosphonium iodide. in this project, phosphonium compounds [c6h5(ch2pph3br)], {c6h4-1-(ch2cl)-3-(ch2pph3cl)} and mercury complexes, [c6h5(ch2pph3)]2[pd2cl2br2],[c6h4-1-(ch2cl)-3-(ch2pph3)]2[pd2cl6] were prepared and characterized. phosphonium salts was prepared from the reaction of 1,3-bis (chloro-methyl)-benzene and tri-phenyl phosphine. then, through the reaction between phosphonium compounds and na2[pd2cl6] final complexes were prepared. next phosphonium salt was prepared from the reaction between benzyl bromide and tri-phenyl phosphine. then, final complexes were prepared through a reaction between phosphonium compounds and na2[pd2cl6].

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